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Q.

A substance A has the following variation of vapour pressure with temperature for its solid state and liquid state. Identify the options which are correct :

Data: For solid A : log10 P=42000T

For liquid A : log10 P=3.481500T

where P is in mm of Hg and T in K.

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a

ΔHsub  will be approximately 9.212 kcal/mol.

b

ΔHfusion  will be approximately 2.303 kcal/mol..

c

Enthalpy of vapourisation and enthalpy of fusion will be temperature independent.

d

ΔHvap. will be approximately 6.909 kcal/moll.

answer is A, B, C, D.

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Detailed Solution

Given,

For solid A : log10 P=42000T

For liquid A : log10 P=3.481500T

Here P is in mm of Hg and T in K.

For this reaction the enthalpy of vapourisation and enthalpy of fusion will be temperature independent. The values of enthalpies for this case,

Sublimation enthply, ΔHsub  = 9.212 kcal/mol.

Enthply of fusion, ΔHfusion = 2.303 kcal/mol..

Vaporization enthply, ΔHvap. = 6.909 kcal/moll.

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A substance A has the following variation of vapour pressure with temperature for its solid state and liquid state. Identify the options which are correct :Data: For solid A : log10 P=4−2000TFor liquid A : log10 P=3.48−1500Twhere P is in mm of Hg and T in K.