Q.

A substance undergoes a change represented as shown A(l) [1 bar, 300 K]  A(s) [1 bar, 300 K]. From the given information, calculate magnitude of change in internal energy (in Joules) when 1 mole of A(l) solidifies.

Information: 
(p) Standard melting point of A(s) is 300 K. 
(q) Latent heat of fusion of A is 0.01 kJ/gm. 
(r) Specific volume ofA(s) is 100 ml/gm and A(l) is 120 ml/gm. 
(s) Molar mass of A is 50 gm / mole

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answer is 400.

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Detailed Solution

In this case change in enthalpy can be given as,

ΔH=0.01×50=0.5  kJ ΔV=65=1LΔU=ΔHΔ(PV) =0.51×1×1001000=0.4 kJ

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