Q.

A substance undergoes a series of chemical reaction as shown 

Ak1Bk2Ck3D with rate constant 

k1=ln22000sec1,k2=ln210sec1,k3=20ln2sec1.

What will be the value of [A][C] once steady state Is obtained?

{[ ] represents concentration}

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a

40000

b

400

c

200

d

20000

answer is A.

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Detailed Solution

At steady state,

k1[A]=k2[B]=k3[C][A][C] k1[A]=k2[B]               =k3k1 k1[A]=k2[B]         =20ln2ln22000 k1[A]=k2[B] =40000

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A substance undergoes a series of chemical reaction as shown A⟶k1B⟶k2C⟶k3D with rate constant k1=ln⁡22000sec−1,k2=ln⁡210sec−1,k3=20ln⁡2sec−1.What will be the value of [A][C] once steady state Is obtained?{[ ] represents concentration}