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Q.

A substance AxBy crystallizes in a face centered cubic lattice in which atoms A occupy each corner of the cube and atoms B occupy the centers of each face of the cube. Identify the correct composition of the substance AxBy.

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a

A3B

b

AB3

c

A4B3

d

composition can not be specified

answer is A.

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Detailed Solution

AxBy forms a face-centered cubic (FCC) lattice as it crystallizes.

Each corner of the cube is occupied by an atom. The result is that A has 8×18=1atoms.

Each face of the cube has a central cluster of B atoms. The total number of atoms in B is therefore 6×12=3.

Consequently, the equation becomes AB3

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