Q.

A symmetrical bridged complex cation made of Co(III), NH3 molecules and oxygen (in the proper ligands form) is found to contain the following ma composition [Atomic  mass of Co= 59] 

Co=36.875%;NH3=53.125%;O=10%The complex cation exists in three ionic forms with cationic charges A:n+; B(n1)+ and C:(n2)+ such that O-O bond length in all of them is found to be more than that. in O2[PtF]. Calculate the value of 11, (n - 1) and (n - 2).

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answer is 654.

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Detailed Solution

Here, the ratio

 Co :  NH3:  O 

36.87559:53.12517:1016

0.625: 3.125: 0.625

1: 5: 1

Co2NH310O2

NH350Co+3O2?Co+3NH35x

0.5 of' O2 can be 0, -1, -2

So, x can be 6, 5, 4.

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