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Q.

(A): The carbon- carbon bond lengths in benzene molecule are 1.54A° and 1.34A°.

(R): Benzene has delocalized pi-bonds.

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a

Both A and R are true. R is not the correct explanation of A

b

A is true but R is false

c

Both A and R are true and R is correct explanation of A

d

A is false but R is true

answer is D.

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Detailed Solution

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  • X-ray data indicates that all the six C—C bond lengths are of the same order (1.39 A°), which is intermediate between C— C single bond (1.54 A°) and C—C double bond (1.33 A°).
  • This is due to the delocalization of pi electrons in the molecule, creating a ring of electron density above and below the plane of carbon atoms. 
  • The delocalization of electrons makes the bonds stronger, leading to a bond length of 1.39 Å, which is intermediate between the length of a single bond (1.54 Å) and a double bond (1.33 Å).
  • Thus, A is false but R is true.
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