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Q.

a) The correct order with respect to the given property are X.
(i) $H_{2} > H e$ : Boiling point order
(ii) $H e > N e > A r > K r > X e$ : Boiling point order
(iii) $S > O > S e > T e$ : electron affinity
(iv) Diamond > graphite : Thermal conductivity order
(v) HF > HI > HBr > HCl : Boiling point order
b) Out of the following configurations which shows Jahn Teller distortion are Y.
i) d⁴ – high spin ii) d⁷ – low spin iii) d⁹
iv) d³ v) d⁴ – low spin vi) d⁷ – high spin
Find the value of $| Y - X |$ is_____.

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Detailed Solution

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(i) $H_{2} > H e$ : Boiling point order
(iv) Diamond > graphite : Thermal conductivity order
(v) HF > HI > HBr > HCl : Boiling point order
The configurations which show JTD are I, II, III, V, VI

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a) The correct order with respect to the given property are X.(i) H2>He : Boiling point order(ii) He>Ne>Ar>Kr>Xe : Boiling point order(iii) S>O>Se>Te : electron affinity(iv) Diamond > graphite : Thermal conductivity order(v) HF > HI > HBr > HCl : Boiling point orderb) Out of the following configurations which shows Jahn Teller distortion are Y.i) d4 – high spin ii) d7 – low spin iii) d9 iv) d3 v) d4 – low spin vi) d7 – high spinFind the value of |Y−X| is_____.