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Q.

(A) :Vapour pressure of 0.5M sugar solution is more than 0.5M KCl solution.
(R) :Lowering of vapour pressure is directly proportional to the number of particles present in the solution.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

Sugar being a covalent compound has formula C12H22O11 where as KClis an ionic compound. 
Since, Relative lowering of vapor pressure (RLVP) is literature driven colligative property, thus it increases with the increase in species present in solution. 
Here, KCl dissociated into K+ and Cl- thus forming two ions in solution and having higher species in solution compared to sugar, thus RLVPsugar>RLVPKCl.
Hence, correct option is: (A)  Both (A) and (R) are true and (R) is the correct explanation of (A) 

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