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Q.

A vessel (A) contains 1 mole each of N2 and O2 and another vessel (B) contains 2 mole each of N2 & O2. Both vessels are heated to same temperature till equilibrium is established in both cases. Then, correct statement is

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a

KC for  N2 + O2 2NO  in A and B are in the ratio 1:2

b

KP for N2 +O2 2NO in A and B are in the ratio 1:2

c

 KC for N2 + O2 2NO in A and B are equal

d

KP for N2 + O2  2NO in A and B are in the ratio 2:1

answer is C.

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Detailed Solution

Equilibrium constant of a reaction depends only on (A) temperature (B) stoichiometry

(A) 1 mole each of N2 and O2 is taken

(B) 2 mole each of N2 and O2 are taken

But temperature is kept constant  therefore  Equilibrium constant (KP (or) KC) remains constant.

KC for N2 + O2 2NO in vessel 'A' and vessel 'B' remains the same.

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