Q.

A vessel contains a mixture of equal weights of oxygen and SO2 at a pressure of 600mm of Hg. The partial pressure of oxygen in mm is

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a

200

b

300

c

400

d

100

answer is C.

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Detailed Solution

Partial pressure of oxygen is equal to product of total pressure and mole fraction of oxygen.

Mole fraction of oxygen=M32

Mole fraction of Sulphur dioxide=M64

Total mole fraction=

M32+M64=3M64

Mole fraction of oxygen=M/323M/64

Mole fraction=⅔

Now according to Dalton's law

=600×2/3

=400 mm of Hg

Hence the correct answer is C

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