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Q.

 A vessel contains a mixture of  NO2 and N2O4  gases. If a pin hole is made in the vessel, then

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a

The partial pressure  NO2 in the gas remaining in the vessel will increase with time.

b

Mole fraction N2O4  in the gas remaining in the vessel will increase with time.

c

Mole fraction NO2 in the gas remaining in the vessel will increase with time.

d

The average molecular weight of gas remaining in the vessel will increase with time.

answer is B, C.

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Detailed Solution

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Being a lighter gas, NO2 diffuses faster

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