Q.

A vessel contains gases at a partial pressures of 1 and 2 atm respectively at certain

            temperature then the reaction.

 8H2S(g) 8H2(g) + S8(s) occurs, It is found that [nH2nH2S]at equilibrium = [nH2SnH2]at time, t = 0

(n represents no. of moles) Then identify the correct value of the given property

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a

KP = 256

b

At equilibrium the volume of the gaseous mixture is doubled when provided with frictionless

piston 

c

KP = 1/256

d

KP = KC = 320

answer is B.

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Detailed Solution

Initially nH2nH2S = 12

8H2S  8H2 + S8

Initial moles                     :       2            1              

moles at equilibrium :          2  x      1 + x      

at equilibrium : nH2nH2S = 1 + x2  x = 2

Hence X = 1, KP = 256

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