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Q.

A vessel (volume 8.2 L) contains H2(g) at 2 atm. pressure. When H2S(g) at a pressure of 4 atm. is introduced into the vessel the reaction 8H2S(g)8H2(g)+S8(s)occurs at a temperature of 2000 K.

It is found that n(H2)n(H2S)at equilibrium=n(H2S)n(H2)at t=0 

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a

Kp=KC(RT)

b

KC=256

c

maximum weight of solid formed is 0.32 g

d

 maximum weight of solid formed is 32 g

answer is D.

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Detailed Solution

8H2S(g)8H2(g)+S8

KC=(4)8(2)8=28=256

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