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Q.

A weak electrolyte having the limiting equivalent conductance of 400 S cm2. equivalent–1 at 298 K is 2% ionized in its 0.1 N solution. 

The resistance of this solution (in ohms) in an electrolytic cell of cell constant 0.4 cm–1 at this temperature is

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a

200

b

300

c

400

d

500

answer is D.

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Detailed Solution

C=0×α=400×2100=8

C=1R×lA×1000NR=1000C×N×lA

R=0.4×10008×0.1=500 ohms

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