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Q.

A weight less piston divides thermally insulated cylindrical vessel into two equal parts. One contains one mole of an ideal gas with adiabatic exponent γ, the other is evaccuated. The initial gas temperature is T0. The piston is released, the gas fills the whole volume of the container. The piston is slowly displaced back to the initial position. Like internal energy U, entropy is another state function of a gas whose change can be calculated as ΔS=dQT, where dQ = Quantity energy in the form of heat which may be either absorbed or ejected by the gas at temperature T. If  ΔU1,ΔS1 denote change in internal energy, change in entropy in the free expansion, and ΔU2,ΔS2  changes in internal energy, change in entropy in the slow compression respectively, then which of the following are correct.

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a

ΔU1=0,ΔS10

b

ΔU20,ΔS2=0

c

ΔU1+ΔU20,ΔS1+ΔS20

d

ΔS10,ΔS20

answer is A, B, C.

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