Q.

(a) Write the product(s) in the following reactions:
(i) Question Image+HCN?
(ii) Question Image +NaOHCaO?Δ
(iii) CH3CH=CHCN (aDIBALH2 ? 
(b) Give simple chemical tests to distinguish between the following pairs of compounds :
(i) Butanal and Butan-2-one
(ii) Benzoic acid and Phenol

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Detailed Solution

(a)
(i)
(ii) Question Image
(iii) CH3CH=CHCN (a) DIBAL-H (b) H2OCH3CH=CHCHO

(b) (i) Butanal and butan-2-one can be distinguished with Tollen’s test. Butanal gives positive test with Tollen's reagent while butan-2-one give negative test.

(ii) Benzoic acid gives a colored buff colored ppt with FeCl3 solution while phenol fives violet color ppt with FeCl3 solution.

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