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Q.

a. Write the products when D-Glucose reacts with Conc. HNO3.
b. Amino acids show amphoteric character. Why?
c. Write one difference between α-helix and β-pleated structures of proteins.

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Detailed Solution

a. Saccharic Acid

On oxidation with nitric acid, glucose as well as gluconic acid both yield a dicarboxylic acid, saccharic acid. This indicates the presence of a primary alcoholic (–OH) group in glucose.

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b. Due to formation of Zwitter ion. In zwitter ionic form, amino acids show amphoteric behavior as they react both with acids and bases. 

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c. α-helix has intramolecular hydrogen bonding and β-pleated structure has intermolecular hydrogen bonding.

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