Q.

(a) Write the reactions involved in the following:
(i) Hoffmann bromamide degradation reaction
(ii) Diazotization
(iii) Gabriel phthalimide synthesis
(b) Give reasons for the following:
(i) (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
(ii) Aromatic diazonium salts are more stable than aliphatic diazonium salts.

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Detailed Solution

a. (i) Hoffmann bromamide degradation reaction
Primary amines can be prepared by Hoffmann degradation.
Question Image
(ii) Diazotization
C6H5NH2+NaNO2+2HCl273278KC6H5N2Cl+NaCl+2H2O
(iii) Gabriel phthalimide synthesis
Question Image
b.(i) Because of the Inductive effect and hydration effect
(ii) Due to resonance structures.

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