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Q.

(a) Write the structures of the main products of the following reactions:
Question Image
(b) Give a simple chemical test to distinguish between Aniline and N, N-dimethylaniline.
(c) Arrange the following in the increasing order of their pKb values
C6H5NH2,C2H5NH2,C6H5NHCH3

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Detailed Solution

a. (i) C6H5NHCOCH3
(ii) C6H5SO2NCH32
(III) C6H6
(b) When chloroform in the presence of KOH and heat, Aniline gives an offensive smell while
N, N-dimethylaniline does not.
(c) C2H5NH2<C6H5NHCH3<C6H5NH2

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