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Q.

A°/2  atoms of X(g) are converted into X(g)+ by absorbing energy E1 . A°/2  ions of  X(g)+ are converted into X(g) with release of energy E2 . Hence ionization energy and electron affinity of X(g) are:

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a

2E1A°,2(E2E1)A°

b

None of these

c

2(E1E2)A°,2E2A°

d

2E1A°,  2(E1E1)A°

answer is B.

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Detailed Solution

X(g)+E1X(g)++e

A02atoms

A02 Atoms absorbs E1 energy

So, 1 atom absorbs  2E1A0  energy

Hence, ionization energy of X(g) is  2E1A0

X(g)+2E1A0X(g)++e      ........eq(1)

X(g)+(A02uons)+2eX(g)+E2

A02  ions release  E2  energy

So, 1 ion releases 2E2A0 energy

Hence, X(g)+(1ion)+2eX(g)+2E2A0      ........eq(2)

Equation for electron affinity of X(g) is, S(g)+eX(g)+EAofX(g)

We can get this equation by adding equation (1) and (2).

X(g)+eX(g)+2(E2E1)A0

Hence, electron affinity of X(g) is 2(E2E1)A0

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