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Q.

A 20 litre container at 400K contains CO2 (g) at pressure 0.4atm and an excess of SrO (neglect the volume of solid SrO ). The volume of the container is now decreased by moving the movable piston fitted in the container. The maximum volume of the container, when pressure of CO2 attains its maximum value, will be

[Given that t:SrCO3(s)SrO(s)+CO2(g),Kp=1.6atm]

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a

2 litre

b

10 litre

c

5 litre

d

4 litre

answer is D.

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Detailed Solution

SrCO3(s)SrO(s)+CO2(g)Kp=PCO2

maximum pressure of CO2 = 1.6atm 

P1V1=P2V20.4×20=1.6V2V2=5L

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