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Q.

(A):2S2O3aq-2+I2SS4O6aq-2+2Iaq- ; (B): S2O3aq-2+2Br2l+5H2Ol2SO4aq-2+4Braq-+10Haq+ 

Different products are given by thiosulphate in (A) and (B) . This is best explained by the fact that

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a

Reaction (A) occurs in alkaline medium

b

Iodine is stronger oxidising agent than Bromine 

c

Iodine is heavier than Bromine 

d

Bromine is stronger oxidising agent than Iodine.

answer is D.

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Detailed Solution

Stronger oxidising agent brings more change in oxidation number of reductant.

A+2S2O3-2 to +2.5S4O6-2; B+2S2O3-2 to +6SO4-2 

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