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Q.

AB and CD are nonvolatile solutes dissolved in the same solvent to obtain two different solutions. For ‘AB’,  'α' is degree of ionization and for ‘CD’, 'β'  is degree of dimerisation  ΔTb(AB)=2.ΔTb(CD). If  α=0.80, then find out 'β'. For AB and CD molar concentrations are same

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Detailed Solution

ΔTb=kcb×m×(1+α) for AB ΔTb'=kb×m×(1β2) for CD ΔTbΔTb1=2=1+α(1β2),1β2=1+α2=1.82=910 β2=110orβ=0.20

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AB and CD are nonvolatile solutes dissolved in the same solvent to obtain two different solutions. For ‘AB’,  'α' is degree of ionization and for ‘CD’, 'β'  is degree of dimerisation  ΔTb(AB)=2. ΔTb(CD). If  α=0.80, then find out 'β'. For AB and CD molar concentrations are same