Q.

AB2 dissociates as : AB2( g)AB(g)+B(g)When the intial pressure of AB2 is 500 mmHg, the total equilibrium pressure is 700 mm Hg. Calculate equilibrium constant for the reaction, assuming that the volume of the system remains unchanged.

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a

214.6 mmHg

b

100 mmHg

c

133.3 mmHg

d

200 mmHg

answer is B.

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Detailed Solution

AB2( g)AB(g)+B(g)

500 mm        0           0

500-x                x              x

Hence,

500-x+x+x=700 

x=200 

Kp=PAB x PBPAB2 

PAB =x=200  PB = x= 200 PAB2 = x =200 

Kp=200×200300=133.3 mm

Hence the correct option is (B) 133.3 mmHg

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