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Q.

A+BCH3OCCH33HIX+Y.
Correct statement among the following is

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a

A and B are CH3OH and CH33COH

b

X and Y are CH3OH and CH33CI

c

X and Y are CH3I and CH33COH

d

A and B are CH3ONa and CH33CBr

answer is C.

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Detailed Solution

Reaction of t-Butyl Methyl Ether with HI

Starting Material: t-butyl methyl ether (CH3-O-C(CH3)3)

Reagent: HI (hydroiodic acid)

The correct statement regarding this reaction is:

When t-butyl methyl ether reacts with HI, it forms methanol (CH3OH) and t-butyl iodide ((CH3)3CI) as products.

Products Formed:

  • Product X: Methanol (CH3OH) - from the methyl group
  • Product Y: t-butyl iodide ((CH3)3CI) - from the t-butyl group

Reaction Mechanism:

  • HI cleaves the ether at the O–CH3 bond due to steric hindrance
  • The reaction proceeds via SN1 pathway
  • Formation of stable t-butyl carbocation intermediate
  • Methyl group forms methanol while t-butyl group forms t-butyl iodide
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