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Q.

A+Bsteam volatile....dil.HNO3phenolConc.HNO3C;  correct oder of Pka values is 

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a

A > B > C

b

B > C > A

c

C > A > B

d

B > A > C

answer is D.

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Detailed Solution

-NO2 group increases the acidic strength of phenol

 acidic strength of    

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This is because in o-nitrophenol, chelation occurs due to intra molecular H-bonding.

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Proton is less available for donation.

Acidic strength of p-nitro phenol>o-nitro phenol>phenol.

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Pka of B>A>C

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