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Q.

According the van der Waal's theory of non-ideal gases, which of the following statement is/are correct?

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a

H2 and He are impossible to liquefy at room temperature.

b

For NH3 , Z decreases more rapidly on increasing pressure than the methane in lower pressure region

c

In the low pressure region, Z decreases on increasing pressure, H2 and He are exception to that.

d

In the high pressure region, Z increases with increasing pressure, H2 and He are exception to that

answer is A, B, C.

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Detailed Solution

Low pressure

Z=1aVmRT

As P,Vm,Z

High pressure 

Z=1+PbRT

As P,Z (including H2 and He)

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