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Q.

According to kinetic theory of gases, which of the following is/are true?

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a

Kinetic energy of the gas molecule does not depend upon P,V and molar mass of the gas molecular

b

the pressure exerted by the gas molecule is proportional to root mean square velocity of the gas molecule

c

Pressure of the gas molecule is proportional to most probable velocity of the gas molecule

d

The root mean square velocity is directly proportional to square root of the kelvin temperature

answer is C, D.

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Detailed Solution

Three Types of Molecular Velocities:

1. Root Mean Square Velocity (crms)

crms = √(3RT/M)

Formula: Square root of (3RT/M)

2. Average Velocity (cave)

cave = √(8RT/πM)

Formula: Square root of (8RT/πM)

3. Most Probable Velocity (cm)

cm = √(2RT/M)

Formula: Square root of (2RT/M)

Where:

  • R = Universal Gas Constant
  • T = Absolute Temperature (in Kelvin)
  • M = Molar Mass of the gas

Answer:

All three formulas shown above are correct according to the kinetic theory of gases.

These are derived from the Maxwell-Boltzmann distribution of molecular speeds.

Relationship:

crms > cave > cm

Average Velocity, r.m.s. Velocity and Most Probable Velocity: Equations -  QS Study

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