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Q.

According to VSEPR theory, what are the bond angles in NH3, H2O and SF6 respectively?

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a

107∘48′;104∘27′;90∘

b

109∘28′;107∘48′;90∘

c

104027′:109∘28′;84030′

d

104∘27′;107∘48′;84∘30′

answer is D.

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Detailed Solution

Question Image

Bond Angles in NH3, H2O, and SF6:

Ammonia (NH3):

  • Molecular geometry: Trigonal pyramidal
  • Electron pair arrangement: Tetrahedral (3 bond pairs and 1 lone pair on nitrogen)
  • The lone pair-bond pair repulsion reduces the ideal bond angle of 109°28′ (tetrahedral angle) to approximately 107°48′.

Water (H2O):

  • Molecular geometry: Bent or V-shaped
  • Electron pair arrangement: Tetrahedral (2 bond pairs and 2 lone pairs on oxygen)
  • The lone pair-lone pair repulsion further reduces the bond angle to approximately 104°27′.

Sulfur Hexafluoride (SF6):

  • Molecular geometry: Octahedral
  • Electron pair arrangement: Octahedral (6 bond pairs and no lone pairs on sulfur)
  • All bond angles in an octahedral geometry are 90°, but slight distortions reduce the bond angle to approximately 84°30′.

Answer:

The bond angles in NH3, H2O, and SF6 are:

  • NH3: 107°48′
  • H2O: 104°27′
  • SF6: 84°30′

Correct Option: d. 104°27′; 107°48′; 84°30′

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