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Q.

Acetic acid and propanoic acid have Ka value 1.75×105 and 1.3×105respectively at a certain temperature, An equimolar so1ution of a mixture, of the two acids is partially neutralised by NaOH. How is the ratio of the contents of acetate and propionate ions related to the Ka values and the molarity?

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a

The ratio is unrelated to the molarity of acid. 

b

α1α=1.751.3×β1β, where a (acetic acid) and β (propanoic acid) are iomsed fractions of their acids.

c

The ratio is unrelated to the Kavalues

d

The ratio is unrelated to the pH of the solution

answer is A, C, D.

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Detailed Solution

HA1-α+OH A+α+H2O

H+=k1×[HA]A=1.75×105×1ααH+=k2×[HPr]Pr=1.3×105×(1β)β

 α1α=1.751.3×β1β

The ratio is unrelated to the molarity of acid and pH of the solution.

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