Q.

Acetone = A, n – butane = B, methoxy ethane = C, Protan – 1 – ol = D ; Propanal = E. Decreasing order of boiling points is

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a

B < C < E < A < D

b

D > A > E > C > B

c

D > E > A > B > C

d

B < C < A < E < D

answer is B.

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Detailed Solution

D > A > E > C > B.

Inter molecular hydrogen bonding in Alcohols;

Dipole-dipole attractions in carbonyl compounds ( Ketones > Aldehydes ).

Weak dipole-dipole attractions in Ethers.

Very weak London dispersion forces in Alkanes.

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Acetone = A, n – butane = B, methoxy ethane = C, Protan – 1 – ol = D ; Propanal = E. Decreasing order of boiling points is