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Q.

Acetone reacts with excess formaldehyde in presence of Alkali condition, then how many number of “-OH” groups are present in reduced form of product

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answer is 6.

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Detailed Solution

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Acetone + Formaldehyde (Alkali) -OH Groups in Product

Organic Chemistry: Reaction of Acetone with Excess Formaldehyde in Alkali

Solution:

  • Acetone (CH3COCH3) reacts with 2 moles of formaldehyde (HCHO) in base (Cross Cannizzaro/Aldol reaction, then reduction).
  • The reduced product is pentane-1,3,5-triol:
  • Structural formula: HOCH2-CH2-C(OH)(CH3)-CH2OH
  • The number of -OH groups in the reduced product is 3.

Final Answer:

There are 3 "-OH" groups in the reduced form of the product.

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