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Acetonitrile when boiled with alkali (or) acid gives

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CH₃ COOH only

CH₃ COOH + H₂

CH₃ COOH + C₂ H₅ OH

CH₃ COOH + NH₃

answer is C.

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Detailed Solution

Hydrolysis of Acetonitrile

Acetic acid (CH₃COOH) and ammonia (NH₃)

CH₃CN + 2 H₂O →[alkali/acid] CH₃COOH + NH₃

On boiling with alkali or acid, acetonitrile undergoes hydrolysis, breaking the C≡N triple bond.
Acetonitrile first forms acetamide, which is further hydrolyzed to acetic acid and ammonia.
The overall products are acetic acid and ammonia.

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