Q.

Acidified potassium dichromate is treated with hydrogen sulphide. In the reaction the oxidation number of chromium?

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a

 increases from +3 to +6

b

decreases from +6 to +3

c

 remains unchanged

d

 decreases from +6 to +2

answer is B.

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Detailed Solution

Dichromate act as a strong oxidizing agent when it is treated withH2S, and then H2S will be oxidized into sulphur.

Cr+62O7-2+3H2S-2+8H+ 2Cr+3+3S0+ 7H2O

K2Cr2O7 act as an oxidizing agent.

Hence, the correct answer is option (B) decreases from +6 to +3.

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Acidified potassium dichromate is treated with hydrogen sulphide. In the reaction the oxidation number of chromium?