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Q.

(a) CoCl34NH3, (b) CoCl35NH3, (c) CoCl36NH3 and (d) CoClNO325NH3

Number of complex(es) which will exist in cis-trans form is/are ____________.

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answer is 1.

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Detailed Solution

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(a)  CoCl34NH3=CoNH34Cl2Cl

                                           Can exhibit G.I.

(b)  CoCl35NH3=CoNH35ClCl2

                                          Can't exhibit G.I.

(c)  CoCl3.6NH3=CoNH36Cl3

                                           Can't exhibit G.I.

(d)  CoClNO325NH3=CoNH35ClNO32

                                              OR

                                      =CoNH35NO3ClNO3

Both can't exhibit G.I.

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