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Q.

Action of conc. nitric acid on metallic tin gives ____ ?

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a

Stannic nitrate

b

Stannous nitrate

c

Stannous nitrite

d

Meta-stannic acid

answer is D.

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Detailed Solution

Most metals dissolve in conc. nitric acid to yield corresponding nitrates and release nitrogen dioxide. But tin produces meta stannic acid.

$S n + c o n c . H N O_{3} \to H_{2} S n O_{3} + H_{2} O + N O_{2}$

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Action of conc. nitric acid on metallic tin gives ____ ?