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Q.

Action of HCl on benzene diazonium chloride in the presence of copper powder gives

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a

p-Chloro benzene diazonium chloride

b

o-Chloro benzene diazonium chloride

c

o-Dichloro benzene

d

Chloro benzene

answer is C.

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Detailed Solution

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Action of HCl on Benzene Diazonium Chloride (with Copper Powder)

Reaction:

C6H5N2Cl + HCl + Cu → C6H5Cl + N2 + CuCl

Main Product: Chlorobenzene (C6H5Cl)

Type of Reaction: Gattermann reaction / Sandmeyer reaction (halogenation of diazonium salt)

What is the mechanism of reaction of benzene diazonium chloride with Zn/HCl?  - Quora

 

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