Activation of benzene ring by $- {NH}_{2}$ in aniline can be decreased by treating with

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Dilute HCl

Ethyl alcohol

Acetic acid

Acetyl chloride

answer is D.

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Detailed Solution

In aniline, the amino group is an electron releasing group.
It activates the benzene ring towards an electrophilic aromatic substitution reaction.
When aniline is acetylated with acetyl chloride, acetanilide is formed.
CH₃CONH− group is less activating group than amino group.
Hence, activation of benzene by −NH₂ group can be reduced by treating the compound with acetyl chloride.

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