Q.

Addition of SnCl2 to HgCl2 gives a ppt. which is :

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a

black turning to white silky

b

white silky turning to greyish black

c

white silky turning to red

d

black silky turning to green

answer is B.

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Detailed Solution

SnCl2is added to HgCl2 to produce the white-to-gray transition precipitate.

2HgCl2+SnCl2Hg2Cl2+SnCl4

Hg2Cl2+SnCl22Hgg+SnCl4

The white Hg2Cl2that is formed subsequently becomes grey result in reduction.

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Addition of SnCl2 to HgCl2 gives a ppt. which is :