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Q.

Adsorption of a gas follows Freundlich adsorption isotherm. x is the mass of the gas adsorbed on mass m of the adsorbent. The plot of versus log p is shown in the given graph. log(x/m) is proportional to

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a

P3/2

b

P3

c

P2

d

P2/3

answer is D.

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Detailed Solution

The Freundlich adsorption isotherm law states that the change in the amount of gas absorbed by unit mass of a solid is directly proportional to the change in the pressure at a given temperature.

Freundlich equation

xm=KP1n-----(I)

Where,

x = mass of the adsorbent at pressure P

k = constant

Taking log both side in equation (I)

log(x/m)=logK+1/ nlog P

According to the given plot

y=mx     where m is slop of line

m=y/x=2/3 

1/n=2/3

So, xmP23

Therefore, option D is correct.

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