Q.

Al3+ has a lower ionic radius than Mg2+ ion because

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a

Mg atom has less number of neutrons than Al

b

Al has a lower ionisation potential than Mg atom.

c

Al and Mg belong to period-3.

d

Al3+ has a higher nuclear charge than Mg2+

answer is B.

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Detailed Solution

Both the species are isoelectronic species, as they all contain the same number of electrons i.e,10.

For isoelectronic species, the size depends upon the effective nuclear charge. More the positive charge, the more the effective nuclear charge, and thus, the lesser the size.

Al3+ has a lower ionic radius than Mg2+ ion because it has a higher nuclear charge than Mg2+.

Hence, option(b) is correct.

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