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Q.

$[A]$ $\overset{Lindlar' s catalyst}{\leftarrow}$ ${CH}_{3} C \equiv C - {CH}_{3}$ $\overset{Na in liq {NH}_{3}}{\to}$ [B] .
[A] and [B] respectively are

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a

Cis, trans – 2 butene

b

Both trans – 2 – butene

c

Both cis – 2 – butene

d

Trans, cis – 2 – butene

answer is A.

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Detailed Solution

$H_{2} /$ Landlar’s catalyst addition is syn addition

$Na / liq {NH}_{3}$ addition is trans addition

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