Q.

All of the following obey Sidgwick effective atomic number rule except :

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a

Ni(CO)4

b

Fe(CO)5

c

V(CO)6

d

K3Fe(CN)6

answer is D.

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Detailed Solution

Due to the fact that the EAN value of Fe in K3[Fe(CN)6] is 35. It doesn't adhere to the EAN rule.

Ni(CO)4  EAN of Ni = 36

Fe(CO)5 EAN of Fe = 36

V(CO)6  EAN of V= 36

K3Fe(CN)6  EAN of Fe = 35

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