All the following cannot liberate hydrogen with alkali except

Metals cannot react with alkalies.

Be, Al, Zn are amphoteric metals. They not only liberate hydrogen gas with acids but also liberate hydrogen gas with alkalies.

$\begin{array}{l}\mathrm{Be}\stackrel{\mathrm{NaOH}}{\to }{\mathrm{Na}}_2{\mathrm{BeO}}_2+{\mathrm{H}}_2;\\ \mathrm{Zn}\stackrel{\mathrm{NaOH}}{\to }{\mathrm{Na}}_2{\mathrm{ZnO}}_2+{\mathrm{H}}_2;\\ \mathrm{Al}\stackrel{\mathrm{NaOH}}{\to }{\mathrm{NaAlO}}_2+{\mathrm{H}}_2;\end{array}$