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Q.

Aluminium chloride exist as dimer Al2Cl6 in solid state as well as in solution of non-polar solvent such as C6H6. When dissolved in water it gives

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a

Al2O3+ 6HCl

b

[Al(H2O)6]3+ + 3Cl–

c

[Al(OH)6]3–+3HCl

d

Al3+ 3Cl–

answer is B.

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Detailed Solution

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AlCl3​ is covalent but in water it becomes ionic due to large hydration energy oh Al3+.

AlCl3+6H2O→AlH2O63++3Cl-

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