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Q.

Aluminium oxide may be electrolysed at 1000°C to furnish aluminium metal (Atomic mass = 27 amu; 1 Faraday = 96,500 Coulombs). The cathode reaction is Al3++3e-AlO

To prepare 5.12 kg of aluminium metal by this method would require

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a

5.49×107C of electricity 

b

1.83×107C of electricity 

c

5.49×104C of electricity 

d

5.49×101C of electricity 

answer is A.

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Detailed Solution

Q=mFZM=5.12×105×96500×327

=5.49×107C

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