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Q.

Aluminium oxide may be electrolysed at 1000oC to furnish aluminium metal (Atomic Mass = 27 amu; 1F = 96,500 C). The cathode reaction is 

Al3++3eAl

To prepare 5.12 kg of aluminium metal by this method would require 

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a

1.83×107C

b

5.49×107C

c

5.49×101C

d

5.49×104C

answer is C.

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Detailed Solution

27 g of Al is obtained by passing a current of 3×96500C.

 1 g of Al is obtained by passing a current of 3×9650027C

5.12×103g of Al is obtained by passing a current of 3×9650027×5.12×1000

                       =1.83×107C×3=5.49×107C

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