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Q.

A M10 solution of potassium ferrocyanide is 46 % dissociated at 18ºC. What will be its osmotic pressure?

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a

10 atm

b

6.8 atm

c

2.4 atm

d

3.5 atm

answer is C.

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Detailed Solution

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K4FeCN61×α→4K+4α+FeCN64-α i=1+4α =1+40.46

π=iCRT =2.84×110×0.0821×291 ≈6.8 atm      

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