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Q.

Amines are produced when an alcoholic solution of ammonia and an alkyl or a benzyl halide is heated in a sealed tube at 373 K. This reaction is called ammonolysis and usually gives a mixture of primary, secondary and tertiary amines along with some quarternary ammonium salts. This reaction is an example of nucleophilic substitution reaction in which ammonia acts as a nucleophile due to the presence of a lone pair of electrons on the nitrogen atom. However this method cannot be used for the preparation of aryl amines. One of the most convenient methods for the preparation of aryl amines is reduction of nitro compounds. Aryl amines can also be prepared by reduction of nitrites or Gabriel phthalimide synthesis.

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