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Q.

Amino -NH2 group is susceptible to oxidation by HNO3, therefore, nitration is done in the presence of

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a

Dil. H2SO4

b

CS2 at 0°C

c

CH3COCl

d

Water

answer is C.

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Detailed Solution

Aniline, when treated with nitric acid and sulphuric acid, forms nitro anilines. P-nitroaniline, m- nitroaniline and o-nitroaniline are formed as products when aniline undergoes nitration.

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The -NH2 group in aniline needs to be protected by acetylation i.e., by treating it with CH3COCl during the nitration process.

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Therefore, option (C) is correct.

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